dc.contributor.author |
Yiğit, Beyhan |
|
dc.contributor.author |
Karaca, Emine Özge |
|
dc.contributor.author |
Yiğit, Murat |
|
dc.contributor.author |
ve öte. |
|
dc.date.accessioned |
2025-08-26T05:31:57Z |
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dc.date.available |
2025-08-26T05:31:57Z |
|
dc.date.issued |
2020 |
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dc.identifier.issn |
0277-5387 |
|
dc.identifier.uri |
http://dspace.adiyaman.edu.tr:8080/xmlui/handle/20.500.12414/6687 |
|
dc.description.abstract |
A series of new ruthenium(II) complexes bearing N-heterocyclic carbene ligands with benzylic groups were prepared by transmetallation reactions between silver(I) N-heterocyclic carbene complexes and [RuCl2(P-cymene)](2). All of the obtained complexes were characterized by FT-IR, H-1 NMR and C-13 NMR spectroscopy, and the molecular structure of compound 3c was also determined by X-ray crystallography. These ruthenium complexes were tested for the alkylation of aromatic amines with a wide range of primary alcohols under solvent-free conditions using the hydrogen borrowing strategy. All of the compounds tested here showed excellent catalytic activity for these reactions and N-monoalkylated products were obtained selectively using 2.5 mol% of the ruthenium complexes. (C) 2019 Elsevier Ltd. All rights reserved. |
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dc.language.iso |
en |
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dc.publisher |
PERGAMON-ELSEVIER SCIENCE LTD |
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dc.subject |
Ru-N-heterocyclic carbene complex |
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dc.subject |
X-ray crystallography |
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dc.subject |
Borrowing hydrogenation reaction |
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dc.subject |
Alkylation of amine |
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dc.title |
Active ruthenium(II)-NHC complexes for alkylation of amines with alcohols using solvent-free conditions |
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dc.type |
Article |
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dc.contributor.authorID |
0000-0003-2094-9742 |
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dc.contributor.authorID |
0000-0001-7487-0007 |
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dc.contributor.department |
Adiyaman Univ, Fac Sci & Art, Dept Chem |
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dc.contributor.department |
Inonu Univ, Catalysis Res & Applicat Ctr, |
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dc.identifier.volume |
175 |
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dc.source.title |
POLYHEDRON |
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