Adıyaman Üniversitesi Kurumsal Arşivi

Active ruthenium(II)-NHC complexes for alkylation of amines with alcohols using solvent-free conditions

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dc.contributor.author Yiğit, Beyhan
dc.contributor.author Karaca, Emine Özge
dc.contributor.author Yiğit, Murat
dc.contributor.author ve öte.
dc.date.accessioned 2025-08-26T05:31:57Z
dc.date.available 2025-08-26T05:31:57Z
dc.date.issued 2020
dc.identifier.issn 0277-5387
dc.identifier.uri http://dspace.adiyaman.edu.tr:8080/xmlui/handle/20.500.12414/6687
dc.description.abstract A series of new ruthenium(II) complexes bearing N-heterocyclic carbene ligands with benzylic groups were prepared by transmetallation reactions between silver(I) N-heterocyclic carbene complexes and [RuCl2(P-cymene)](2). All of the obtained complexes were characterized by FT-IR, H-1 NMR and C-13 NMR spectroscopy, and the molecular structure of compound 3c was also determined by X-ray crystallography. These ruthenium complexes were tested for the alkylation of aromatic amines with a wide range of primary alcohols under solvent-free conditions using the hydrogen borrowing strategy. All of the compounds tested here showed excellent catalytic activity for these reactions and N-monoalkylated products were obtained selectively using 2.5 mol% of the ruthenium complexes. (C) 2019 Elsevier Ltd. All rights reserved. tr
dc.language.iso en tr
dc.publisher PERGAMON-ELSEVIER SCIENCE LTD tr
dc.subject Ru-N-heterocyclic carbene complex tr
dc.subject X-ray crystallography tr
dc.subject Borrowing hydrogenation reaction tr
dc.subject Alkylation of amine tr
dc.title Active ruthenium(II)-NHC complexes for alkylation of amines with alcohols using solvent-free conditions tr
dc.type Article tr
dc.contributor.authorID 0000-0003-2094-9742 tr
dc.contributor.authorID 0000-0001-7487-0007 tr
dc.contributor.department Adiyaman Univ, Fac Sci & Art, Dept Chem tr
dc.contributor.department Inonu Univ, Catalysis Res & Applicat Ctr, tr
dc.identifier.volume 175 tr
dc.source.title POLYHEDRON tr


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